They are used in vapor compression processes with all types of compressors. This is a relative indication of the effect of the substance on breaking down the ozone layer. Montreal protocol agreement for reducing odp refrigerants. They also have good energy efficiency, but are flammable and can form an explosive mixture with air if a leak occurs. Nextgeneration low global warming potential refrigerants. R4a is widely used in automotive air conditioning and residential, commercial and industrial refrigeration systems, but also as a blowing agent for rigid. Products that normally contain ozone depleting substances should be replaced with functionally similar products that contain nonozone depleting substances.
Odp is expressed as a relative potential of ozone depletion compared to influence of r11 which has odp1. Pdf refrigerant types, issues, trends and future options. The hydrofluorocarbons are refrigerants that contain no chlorine and are not harmful to the ozone layer odp 0, see section 5. The regulation for the management of high global warming potential refrigerants for stationary sources carb. Linde strongly advocates the use of refrigerant gases with zero ozone depletion. R404a is a ternary refrigerant blend consisting of the hfc r125 fortyfour percent, hfc r143a fiftytwo percent, and hfc r4a four percent. Ozone depletion potentials odps were a very important measure in the formulation of the montreal protocol and its amendments.
July 1, 1992 which of the following refrigerants have. The most common hfc refrigerants available since the ban on hcfcs are presented in table 5. Chlorine interacts with ozone, converting it into oxygen and taking away its beneficial properties. Global warming potential gwp is a measure of how much a given mass of a gas contributes to global warming. R427a like other gases such as r407c is a zeotrope. Indicators for quantitative comparison of the various substancesareodp8ozonedepletionpotentialandgwp9 global warming potential, which are closely related to their atmospheric lifetime alt 10. A viable lowgwp candidate must possess a number of other attributes 6, including zero or very low ozonedepletion potential, chemical stability within the. Linde strongly advocates the use of refrigerant gases with zero ozone depletion potential and fully supports the phase out of hcfcs. It went into effect in 1987, first targeting cfcs, then hcfcs. Refrigerant product information opteon xp10 r5a is a non ozone depleting, low global warming potential gwp hydrofluoroolefin hfo based refrigerant developed to replace r4a in positive displacement, direct expansion, mediumtemperature commercial and industrial chillers, as well as flooded andor centrifugal chillers. Refrigerant gases containing chlorine or bromine have a high ozone depletion potential odp and damage the planets ozone layer. R22 phaseout timeline 1999 100 50 0 % 1996 cap 100% 65% 25% 10% us eu a5 nations today 6 32. Use of climate friendly refrigerants is recommended by edge. Common refrigerants and their ozone depletion potential odp and global warming potential gwp are indicated below.
Dec 21, 2017 the odp or ozone depletion potential, is the potential for a single molecule of the refrigerant to destroy the ozone layer. Compared to halogenated refrigerants, hydrocarbons like isobutane r600a and propane r290 offer several advantages. Chlorodifluoromethane r22, for example, has an odp of 0. Halogenated hydrocarbons, especially chlorofluorocarbons cfcs, are a major cause of ozone layer depletion because of the amounts of chlorine atoms that are part of their makeup. In order to reduce the depletion of ozone and reverse the climate change effects, the european union legislation 2014 and paris accord 2016 are strongly emphasizing the phasing out of the use of harmful synthetic refrigerants. Refrigerants r407c and r407a properties, uses, storage. July 1, 1992 which of the following refrigerants have the lowest ozone depletion potential odp. For each ods, this page provides the compounds atmospheric lifetime, ozone depletion potential ozone depletion potentiala number that refers to the amount of ozone depletion caused by a substance. Cfcs technicians have been required to be certified to service, maintain, or dispose of appliances containing regulated refrigerants since. Environmental and safety considerations most commercially available refrigerants are safe for humans and working spaces. Odp values are used to provide a simple way to compare the relative ability of various ods to destroy stratospheric ozone. Ashrae position document on refrigerants and their. It operates at higher pressures than many other refrigerants, and so cannot be used to retrofit r22 systems. Ozonedepleting substances ozone layer protection us epa.
The emission of ozone depleting substances has been damaging the ozone layer. Footscray, victoria table 1 global warming and ozone depletion potential of anaesthetics chemical formula lifetime yrs isoflurane chf. Refrigerant selection to reduce climate impact edge buildings. However, their impact on global warming is very large compared with traditional refrigerants. Highglobal warming potential highgwp refrigerants include all ozonedepleting substances and any refrigerant with a gwp of 150 or higher. It is very important to recover the refrigerants cfc hcfc hfc and. A viable lowgwp candidate must possess a number of other attributes 6, including zero or very low ozone depletion potential, chemical stability within the refrigeration system, thermodynamic.
Choice of natural refrigerants makes no net addition of the greenhouse gases ghg in the environment. Environmental management of refrigeration equipment pdf, 151kb. However, they have an impact on the environment by contributing to global warming andor ozone depletion. R111, 2 global warming potential 100 year, ipcc 4th assessment report, 2007. The current generation of refrigerants, hydrofluorocarbons hfcs, have zero ozone depletion potential. Limited options for lowglobalwarmingpotential refrigerants. Refrigerants can thus also be ranked according to their impact on the stratospheric ozone layer the ozone depletion potential, odp or as greenhouse gases the global warming potential, gwp. As a result of ozone depletion in the upper atmosphere, m. Cfc 11, or r11 has the maximum potential amongst chlorocarbons because of. Stratospheric ozone protects us from ultraviolet rays. Odp is defined as the integrated change in total ozone per unit mass. When did it become unlawful to intentionally release class i and class ii refrigerants into the atmosphere. Because cfcs and hcfcs contain chlorine, which has ozone depletion potential odp, the montreal protocol focused on phasing out cfcs and hcfcs.
Since india already receives high doses of ultraviolet uvb radiation, and is at the threshold go to speak, effects of ozone layer depletion. All of the refrigerants use r11 as a calibration and thus r11 has an odp of 1. Ozone depletion potential article about ozone depletion. The odp is the ratio of the impact on ozone of a chemical compared to the impact of a similar mass of cfc11. But through domestic and international action, the ozone layer is healing and should fully recover by about 2065. Ozone is depleted by chlorinecontaining compounds that reach the upper atmosphere. Protection of ozone layer and prevention of global warming have become a major issue of. Ozone depletion potential of different refrigerants.
Ozone depletion potential odp of a chemical compound is the relative amount of degradation it can cause to the ozone layer. The common hfcs are efficient and classified as a1 lower toxicity no flame propagation. R4a tetrafluoroethane is an environmental non ozone depleting refrigerant, the cooling capacity and efficiency and r12 is very close, they were regarded as longterm alternative to r12. The effects on the industry of the actions to reduce ozone depletion and global warming are now apparent. Odp is defined as the integrated change in total ozone per unit mass emission of a specific ozonedepleting substance relative to the integrated change in total ozone per unit mass emission of cfc11 wmo, 1995, i.
The greatest concentration of ozone are found from 12 km to 50 km above the earth forming a layer in the stratosphere which is called the ozone layer. Natural and synthetic refrigerants, global warming. Hydrocarbon refrigerants are flammable, nontoxic, zero odp ozone depletion potential and very low gwp global applications. It mandates that all refrigerants with odp will be phased. The global warming potential gwp is the relative measure of the substance impact on the greenhouse effect in relation to the impact of a kilogram of co 2. Odp is ozone depletion potential of with re ference to cfc r11 as 1.
Refrigerants and cfcs a major cause of ozone layer depletion. Which of the following has the highest ozone depletion potential. Mar, 2017 hfcs successfully dealt with the concerns of ozone depletion, but environmental acceptability is a moving target. All of the refrigerants use r11 as a datum reference and thus r11 has an odp of 1. This website addresses stratospheric ozone issues, including the science of ozone depletion, epas regulatory approach to protecting the ozone layer, epa. Global warming potential gwp is a measure of how much a given mass of a gas contributes to global. It discusses the effects of ozone depletion, the benefits of the cfc phaseout, the present and future alternatives to cfc refrigerants.
The less the value of the odp the better the refrigerant is for the ozone layer and therefore the environment. Refrigerants are regulated as hazardous materials by the us epa and carb, due to their ozone depleting ability and powerful greenhouse gas potential. The less the value of the odp the better the refrigerant is for the ozone layer and the environment. Refrigerants ozone depletion odp and global warming potential gwp common refrigerants and their ozone depletion potential odp and global warming potential gwp are indicated below. Nonozone depleting substances ods do not deplete the earths protective ozone layer. Cfcs were replaced with hcfcs, which have lower ozone depletion potential odp, or with. The ozone depletion potential odp of a chemical compound is the relative amount of degradation to the ozone layer it can cause, with trichlorofluoromethane r11 or cfc11 being fixed at an odp of 1. The low ozone depletion potential of r22 compared to cfc11 chlorofluorocarbon 11 and cfc12 and its excellent refrigerant properties have helped facilitate the transition away from cfcs. Explain ozone depleting potential of conventional refer gases. Systems designed for r410a can take advantage of its ability to use smaller components, making it a key refrigerant for domestic and light air conditioning equipment. Refrigerant types, issues, trends and future options. Ozone is a variant of oxygen, the ozone molecule having three atoms of oxygen. Refrigerants containing chlorine or bromine contribute to the breakdown of the ozone layer see figure 5. Substances with high global warming potential gwp are a key concern.
Add r427a, with an initial charge of 95% of the original weight. Environmental concerns have caused ozone depleting potential odp, global warming potential gwp, energy efficiency, and lifecycle climate performance lccp iir 2016 to become important factors in thedesign and use of equipment. The use of hydrocarbon refrigerants is becoming increasingly popular due to their low environmental impact and excellent thermodynamic performance. R410a is an hfc blend designed for new r22 applications. Global warming potential vs ozone depletion potential. Zero ozone depletion potential replacement for r22. In most cases no timeconsuming circuit rinsing is required. Gwp values for ozone depleting substances can range, for example, from 2 up to about 14,000.
We recognized as far back as 1987 that hfcs have high global warming potential gwp, but their gwp was lower than the cfcs that they replaced, and at the time we thought that. Copenhagen amendments of the montreal protocol and the consideration of possible further options. Ozone depletion and global warming are two major environmental concerns with serious implications for the future development of the refrigerationbased industries. The odp, or ozone depletion potential, is the potential for a single molecule of the refrigerant to destroy the ozone layer. But we are all part of the problem, simply because many of the products we use every day can release ozone depleting substances into the atmosphere.